{"id":3479,"date":"2014-10-14T09:28:33","date_gmt":"2014-10-14T13:28:33","guid":{"rendered":"http:\/\/regulatory.blog\/?p=3479"},"modified":"2025-09-08T02:08:15","modified_gmt":"2025-09-08T06:08:15","slug":"corrosive-or-not-corrosive","status":"publish","type":"post","link":"https:\/\/www.thecompliancecenter.com\/ca\/help-center\/articles\/corrosive-or-not-corrosive\/","title":{"rendered":"Corrosive or Not Corrosive?"},"content":{"rendered":"<h2>What Do the Regulations Say?<\/h2>\n<p>Normally when considering whether or not a material or substance is to be assigned to Class 8, the preferred method is an in vivo (living animal) or in vitro (&#8220;in glass&#8221; or simulated test-tube) determination of the effect of the sample on living tissue. In addition the effect of corrosion of metals is considered for the lower hazard (PG III) aspect of the class.<\/p>\n<p>I had a question the other day wherein a sample of a material tested &#8220;positive&#8221; according to the UN Manual of Test Procedures (5th Ed.), Part III, 37 yet the classification was being questioned by a (dedicated) potential carrier. The material tested &#8220;pitted&#8221; the standard aluminum alloy to a depth greater than that specified in the 37.4.1.4.2 (&#8220;localized&#8221;) criteria. The consignor classified the material as Corrosive based on the consulting lab&#8217;s report of this result which stated that the product was a &#8220;candidate for &#8230; Class 8&#8221;. The trouble was that the sample was negative in the &#8220;uniform&#8221; (37.4.1.4.1- equivalent to the 6.25 mm\/y criteria) portion of the test.<br \/>\n<!--more--><\/p>\n<p>The latter is the only criteria currently referenced for Class 8 when considering effects on metal.<\/p>\n<h3>How this could become confusing<\/h3>\n<p><strong>i.e. The wording in the various regulations do not say the equivalent of:<\/strong><br \/>\n&#8220;The substance is Class 8, PG III if a positive result is obtained in UN test 37.4&#8221;;<\/p>\n<p><strong>but do say the equivalent of:<\/strong><br \/>\n&#8220;The substance is Class 8, PG III if you get a positive result in a uniform corrosion test (equivalent to 6.25 mm\/y) such as UN test 37.4&#8221;.<\/p>\n<p>The above is consistent within the IMDG Code, IATA DGR, US 49CFR \u2013 all of which reference the UN Manual of Tests as an example of an acceptable protocol- and Canada\u2019s TDGR. The Canadian TDGR classification wording is the same- only quoting ASTM G 31-72 (reappr.1995) as the reference method. ASTM G 31 also has both criteria available. The UN Model TDG (\u201cOrange Book\u201d) regulations (perhaps ironically) use the same wording as IMDG, and others. However the Orange Book does indicate that the &#8220;competent authority has discretion to dispense with certain tests&#8230;&#8221; in section 1.1.2.<\/p>\n<p>This illustrates the necessity of having copies of the regulations (see Samantha&#8217;s Blog of Sept.16)- and often the referenced standards- to consult when determining how to assign a classification to a material.<\/p>\n<p>Where regulations (such as Canada&#8217;s recent amendment to require documentation of a &#8220;proof of classification&#8221; \u2013 along with the general requirement to not give a false indication of a hazard) expect the consignor\/shipper to justify the assigned classification, the issue can be significant beyond having a carrier question a specific shipment.<\/p>\n<p>As always, if you have questions about this topic or any other regulatory needs, please give us a call in the US at (888) 442-9628 or in Canada at (888) 977-4834 and talk to one of our regulatory specialists or customer relations representatives.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>What Do the Regulations Say? Normally when considering whether or not a material or substance is to be assigned to&#8230;<\/p>\n","protected":false},"author":12552,"featured_media":5062,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"content-type":"","footnotes":""},"categories":[2413,5073,5074,5076,5078],"tags":[2778],"class_list":["post-3479","post","type-post","status-publish","format-standard","has-post-thumbnail","category-tdg-regulation-updates","category-dot-49-cfr","category-tdgr","category-iata","category-imdg","tag-corrosives"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.6 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Confusion Over Corrosives<\/title>\n<meta name=\"description\" content=\"Why might a shipper and a carrier disagree on the classification of corrosives under TDG? 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